HARRY R. ALLCOCK Research Group Publications. Two separate lists are provided. This list gives publications organized by topic and in the order of their publication, plus sections on review articles, book chapters, books, and patents. The other list is a total compilation of publications, with the most recent listed first. This can be accessed through the Publications Chronological button on the left.
SELECTED PUBLICATIONS ORGANIZED BY TOPIC
(Publication numbers are out of a total of 519 as of January 2007)
CLICK ON A TOPIC BELOW - TO GO TO THE RELATED TOPIC REFERENCES
A. PUBLICATIONS ON FUNDAMENTAL POLYMER CHEMISTRY
B. SMALL-MOLECULE MODEL CHEMISTRY
C. PUBLICATIONS ON BIOMEDICAL MATERIALS
D. PUBLICATIONS RELATED TO OPTICS, ELECTRONICS, AND PHOTONICS
F. SURFACE SCIENCE AND COMPOSITE MATERIALS
G. CLATHRATE (MOLECULAR INCLUSION) CHEMISTRY
A. PUBLICATIONS ON FUNDAMENTAL POLYMER CHEMISTRY
7. Allcock, H. R.; Best, R. J.
The Mechanism of Phosphonitrilic Chloride Polymerization. Capacitance, Conductance, and Electron‑Spin Resonance Studies
Can. J. Chem. 1964, 42, 447‑455.
12. Allcock, H. R.; Kugel, R. L.
Synthesis of High Polymeric Alkoxy‑ and Aryloxyphosphonitriles
J. Am. Chem. Soc. 1965, 87, 4216‑4217
14. Allcock, H. R.; Kugel, R. L.; Valan, K. J.
High Molecular Weight Poly(alkoxy‑ and aryloxyphosphazenes)
Inorg. Chem. 1966, 5, 1709‑1715.
15. Allcock, H. R.; Kugel, R. L.
High Molecular Weight Poly(diaminophosphazenes)
Inorg. Chem. 1966, 5, 1716‑1718.
33. Allcock, H. R.; Moore, G. Y.
Synthesis of Poly(organophosphazene) Copolymers and Crosslinked Polymers by Ligand Exchange
Macromolecules 1972, 5, 231‑232.
36 Allcock, H. R.; Kugel, R. L.; Stroh, E. G.
The Structure and Properties of Poly(difluorophosphazenes)
Inorg. Chem. 1972, 11, 1120‑1123.
48. Allcock, H. R.; Gardner, J. E.; Smeltz, K. M.
Polymerization of Hexachlorocyclotriphosphazene. The Role of Phosphorus Pentachloride, Water, and Hydrogen Chloride
Macromolecules 1975, 8, 36‑42.
49. Allcock, H. R.; Moore, G. Y.
Polymerization and Copolymerization of Phenyl‑halogenocyclotriphosphazenes
Macromolecules 1975, 8, 377‑382.
24. Allcock, H. R.; Mack, D. P.
High Molecular Weight Poly(diaminophosphazenes) with Mixed Substituents
J. Chem. Soc., Chem. Commun. 1970, 11, 685.
37. Allcock, H. R.; Cook, W. J.; Mack, D. P.
High Molecular Weight Poly[bis(amino)phosphazenes] and Mixed Substituent
Poly(aminophosphazenes), Inorg. Chem. 1972, 11, 2584‑2590.
44. Allcock, H. R.; Cook, W. J.
Thermolysis of Poly[bis(trifluoroethoxy)phosphazene]
Macromolecules 1974, 7, 284‑290.
45. Allcock, H. R.; Moore, G. Y.; Cook, W. J.
The Thermal Breakdown of Poly(diphenoxyphosphazene)
Macromolecules 1974 7, 571575.
57. Allcock, H. R.; Allen, R. W.; Meister, J. J.
Conformational Analysis of Poly(dihalophosphazenes)
Macromolecules 1976, 9, 950‑955
58. Allen, R. W.; Allcock, H. R.
Conformational Analysis of Poly(alkoxy‑ and aryloxyphosphazenes)
Macromolecules 1976, 9, 956‑960.
60. Allcock, H. R.; Patterson, D. B.
Ring‑Ring and Ring‑Chain Equilibration of Dimethylphosphazenes.
Relationship to Phosphazene Polymerization
61. Allcock, H. R.; Allen, R. W.; O'Brien, J. P.
Synthesis of Platinum Derivatives of Polymeric and Cyclic Phosphazenes
J. Am. Chem. Soc. 1977, 99, 3984‑3987
64. Allcock, H. R.; Patterson, D. B.; Evans, T. L.
Synthesis of Alkyl and Aryl Phosphazene High Polymers
J. Am. Chem. Soc. 1977, 99, 6095‑6096.
68. Allcock, H. R.; Schmutz, J. L.; Kosydar, K. M.
A New Route for Poly(organophosphazene) Synthesis. Polymerization, Copolymerizaton, and Ring‑Ring Equilibration of Trifluoroethoxy‑ and
Chloro‑substituted Cyclotriphosphazenes
Macromolecules 1978, 11, 179‑186.
72. Allcock, H. R.; Patterson, D. B.; Evans, T. L.
Synthesis of Open‑Chain Poly(difluorophosphazene) and its Reactions with Alkoxides
Macromolecules 1979, 12, 172‑177.
79. Allcock, H. R.; Chu, C. T.‑W.
The Reaction of Phenyllithium with Poly(dichlorophosphazene)
Macromolecules 1979, 12, 551‑555.
81. Ritchie, R. J.; Harris, P. J.; Allcock, H. R.
Polymerization of Monoalkyl‑pentachloro‑cyclotriphosphazenes
Macromolecules 1979, 12, 1014‑1015.
82. Allcock, H. R.; Evans, T. L.; Patterson, D. B.
The Reaction of Poly(difluorophosphazene) with Phenyllithium
Macromolecules 1980, 13, 201‑207.
85. Allcock, H. R.; Arcus, R. A.
Crystalline Transitions and Related Physical Properties of Poly(dichloro‑phosphazene)
Macromolecules 1979, 12, 1130‑1136.
89. Allcock, H. R.; Arcus, R. A.; Stroh, E. G.
X‑Ray Diffraction Analysis of the Stucture of Poly(dichlorophosphazene)
Macromolecules 1980, 919‑928.
94. Allcock, H. R.; Fuller, T. J.; Evans, T. L.
Side Group Construction in High Polymeric Phosphazenes Via Lithiophenoxy Intermediates
Macromolecules 1980, 13, 1325‑1332.
95. Allcock, H. R.; Ritchie, R. J.; Harris, P. J.
Synthesis of Alkylphosphazene High Polymers Via the Polymerization of Monoalkylpentachlorocyclotriphosphazenes, N3P3Cl5R
Macromolecules 1980, 13, 1332‑1338.
99. Allcock, H. R.; Scopelianos, A. G.; O'Brien, J. P.; Bernheim, M. Y.
Synthesis and Structure of Carborane‑Substituted Cyclic and Polymeric Phosphazenes
J. Am. Chem. Soc. 1981, 103, 350‑357.
101. Evans, T. L.; Allcock, H. R.
Poly(difluorophosphazene): A New Intermediate for the Synthesis of Poly‑(organophosphazenes)
J. Macro. Sci. ‑ Chem. (Proc. of Symp. on Inorganic Macromolecules) 1981, A16(1), 409‑423.
107. Evans, T. L.; Patterson, D. B.; Suszko, P. R.; Allcock, H. R.
A Crosslinking Mechanism in the Reactions of Poly(difluorophosphazene) with Alkyllithium Reagents
Macromolecules 1981, 14, 218‑221.
109. Allcock, H. R.; Austin, P. E.; Rakowsky, T. F.
Diazo Coupling Reactions with Poly(organophosphazenes)
Macromolecules 1981, 14, 1622‑1625.
116. Allcock, H. R.; Ferrar, W. T.; Levin, M. L.
Polymerization in Clathrate Tunnel Systems: Stereo‑Controlled Polymerization of Unsaturated Monomers in Crystals of
Tris(o‑phenylenedioxy)cyclotri‑phosphazene
Macromolecules 1982, 15, 697‑703.
124. Allcock, H. R.; Scopelianos, A. G.; Whittle, R. R.; Tollefson, N. M.
Cyclic and High Polymeric Carboranyl Phosphazenes as Ligands for Transition Metals
J. Am. Chem. Soc. 1983 105, 1316‑1321.
127. Austin, P. E.; Riding, G. H.; Allcock, H. R.
An Improved Method for the Synthesis of Poly(organophosphazenes) and Hindered Cyclophosphazenes
Macromolecules 1983, 16, 719‑722.
130. Allcock, H. R.; Hymer, W. C.; Austin, P. E.
Diazo Coupling of Catecholamines with Poly(organophosphazenes)
Macromolecules 1983, 16, 1401‑1406.
145. Scopelianos, A. G.; Allcock, H. R.
Solution Polymerization of Chlorocyclophosphazenes in Carbon Disulfide
Macromolecules 1987, 20, 432‑433.
148. Allcock, H. R.; Brennan, D. J.; Allen, R. W.
Reactions between Hexachlorocyclotriphosphazene and Hexamethylcyclotri‑siloxane: Polymerization, Ring Cleavage, and Crosslinking
Inorganic Chemistry 1985, 18, 139‑144.
149. Allcock, H. R.; Levin, M. L.
The Stereocontrolled Polymerization of Acrylic Monomers Within a Tris‑(o‑phenylenedioxy)cyclotriphosphazene Tunnel Clathrate
Macromolecules 1985, 18, 1324‑1330.
150. Allcock, H. R.; Connolly, M. S.
Polymerization and Halogen Scrambling Behavior of Phenyl‑Substituted Cyclotriphosphazenes
Macromolecules 1985, 18, 1330‑1340.
151. Allcock, H. R.; Lavin, K. D.; Riding, G. H.
Ring‑Opening Polymerization of Metallocene Cyclophosphazene Derivatives
Macromolecules 1985 18, 1340‑1345.
159. Dubois, R. A.; Garrou, P. E.; Lavin, K. D.; Allcock, H. R.
Cobalt Hydroformylation Catalyst Supported on a Phosphinated Polyphosphazene: Identification of Phosphorus‑Carbon Bond Cleavage as a
Mode of Catalyst Deactivation
Organometallics 1986, 5, 460‑466.
160. Allcock, H. R.; Riding, G. H.; Lavin, K. D.
Polymerization of New Metallocenylphosphazenes
Macromolecules 1987, 20, 6‑10.
176. Allcock, H. R.; Mang, M. N.; McDonnell, G. S.; Parvez, M.
Transition Metal Derivatives of Polyphosphazenes: Syntheses of Polyphosphazenes and Cyclic Model Compounds with Iron Cyclopentadienyl
Carbonyl Side Groups
Macromolecules 1987, 20, 2060‑2067.
181. Allcock, H. R.; Brennan, D. J.; Graaskamp, J. M.
Ring‑Opening Polymerization of Methylsilane‑ and Methylsiloxane‑Substituted Cyclotriphosphazenes
Macromolecules 1988, 21, 1‑10.
182. Allcock, H. R.; Connolly, M. S.; Sisko, J. T.; Al‑Shali, S.
Effects of Organic Side Group Structures on the Properties of Poly‑(organophosphazenes)
Macromolecules 1988, 21, 323‑334.
183. Allcock, H. R.; Desorcie, J. L.; Rutt, J. S.
Alkylation of Cyclic and High Polymeric Phosphazenes via Reactions between Aluminum Alkyls and Aminophosphazenes
Organometallics 1988, 7, 612‑619.
186. Allcock, H. R.; Brennan, D. J.
Organosilicon Derivatives of Cyclic and High Polymeric Phosphazenes
J. Organomet. Chem., 1988, 341, 231‑239.
194. Allcock, H. R.; Brennan, D. J.; Dunn, B. S.
Synthesis of Polyphosphazenes Bearing Geminal Trimethylsilylmethylene and Alkyl or Phenyl Side Groups
Macromolecules 1989,22, 1534‑1539.
199. Manners, I.; Riding, G. H.; Dodge, J. A.; Allcock, H. R.
Role of Ring Strain and Steric Hindrance in a New Method for the Synthesis of Macrocyclic and High Polymeric Phosphazenes
J. Am. Chem. Soc. 1989, 111, 3067‑3069.
201. Allcock, H. R.; Mang, M. N.; Dembek, A. A.; Wynne, K. J.
Poly(aryloxyphosphazenes) with Phenylphenoxy and Related Bulky Side Groups. Synthesis, Thermal Transition Behavior, and Optical Properties
Macromolecules 1989, 22, 4179‑4190.
205. Manners, I.; Renner, G.; Nuyken, O.; Allcock, H. R.
Polycarbophosphazenes: A New Class of Inorganic‑Organic Macromolecules
J. Am. Chem. Soc. 1989, 111, 5478‑5480.
207. Allcock, H. R.; Coggio, W. D.
Organosiloxyphosphazene Polymers: Synthesis via Aminosiloxane Reagents
Macromolecules 1990, 23, 1626‑1635.
209. Dodge, J. A.; Manners, I.; Allcock, H. R.; Renner, G.; Nuyken O.
Polythiophosphazenes: New Inorganic Macromolecules with Backbones Composed of Phosphorus, Nitrogen, and Sulfur Atoms
J. Am. Chem. Soc. 1990, 112, 1268‑1269.
211. Brennan, D. J.; Graaskamp, J.; Dunn, B. S.; Allcock, H. R.
Organosilicon Derivatives of Cyclic and High Polymeric Phosphazenes
Inorg. Synth. 1989, 25, 60‑68
214. Allcock, H. R.; McDonnell, G. S.; Desorcie, J. L.
Synthesis of New Polyphosphazene Elastomers
Macromolecules 1990, 23, 3873‑3877.
218. Allcock, H. R.; McDonnell, G. S.; Desorcie, J. L.
Ring Expansion and Equilibration in Organophosphazenes, and the Relationship to Polymerization
Inorganic Chemistry 1990, 29, 3839‑3844.
224. Allcock, H. R.; Coley, S. M.; Manners, I.; Renner, G.; Nuyken, O.
Poly[(aryloxy)carbophosphazenes]: Synthesis, Properties, and Thermal Transition Behavior
Macromolecules 1991, 24, 2024‑2028.
225. Visscher, K, B.; Manners, I.; Allcock, H. R.
Interpenetrating Polymer Networks of Poly(organophosphazenes) and Organic Polymers
Macromolecules 1990, 23, 4885‑4886.
229. Allcock, H. R.; Rutt, J. S.; Welker, M. F.; Parvez, M.
Cyanophosphazene Small Molecules and High Polymers: Synthesis and Structure
Inorganic Chemistry 1993, 32, 2315‑2321.
231. Allcock, H. R.; Rutt, J. S.
Synthesis of Polyphosphazenes with Isothiocyanato, Thiourethane, and Thiourea Side Groups
Macromolecules 1991, 24, 2852‑2857.
235. Allcock, H. R.; Rutt, J. S.; Fitzpatrick, R. J.
A Surface Reaction of Poly[bis(trifluoroethoxy)phosphazene] Films by Basic Hydrolysis
Chemistry of Materials 1991, 3, 442‑449.
240. Allcock, H. R.; Fitzpatrick, R. J.
Functionalization of the Surface of Poly[bis(trifluoroethoxy)phosphazene] by Reactions with Alkoxide Nucleophiles
Chemistry of Materials 1991, 3, 450‑454.
245. Ngo, D. C.; Rutt, J. S.; Allcock, H. R.
Poly(phosphazophosphazenes): A New Class of Inorganic Polymers with Short‑Chain Branching
J. Am. Chem. Soc. 1991, 113, 5075‑5076.
250. Allcock, H. R.; Dodge, J. A.; Manners, I.; Riding, G. H.
Strain‑Induced Ring‑Opening Polymerization of Ferrocenylorganocyclotriphosphazenes: A New Synthetic Route to Poly(organophosphazenes)
J. Am. Chem. Soc. 1991, 113, 9596‑9603.
252. Allcock, H. R.; Fitzpatrick, R. J.
Sulfonation of Aryloxy‑ and Arylamino‑Phosphazenes: Small‑Molecule Compounds, Polymers, and Surfaces
Chemistry of Materials 1991, 3, 1120‑1132.
256. Allcock, H. R.; Ngo, D. C.
Synthesis of Poly(bis‑phosphazo)phosphazenes Bearing Aryloxy and Alkoxy Side Groups
Macromolecules 1992, 25, 2802‑2810.
258. Allcock, H. R.; Fitzpatrick, R. J.; Salvati, L.
Oxidation of Poly[di(4‑methylphenoxy)phosphazene] Surfaces, and Chemistry of the Surface Carboxylic Acid Groups
Chemistry of Materials 1992, 4, 769‑775.
268. Allcock, H. R.; Turner, M. L.
Ring Expansion and Polymerization of Transannular‑Bridged Cyclotri-phosphazenes and Their Spirocyclic Analogues
Macromolecules 1993, 26 3‑10.
269. Allcock, H. R.; Visscher, K. B.; Manners, I.
Polyphosphazene‑Organic Polymer Interpenetrating Polymer Networks
Chemistry of Materials 1992, 4, 1188‑1192.
271. Allcock, H. R.; Fitzpatrick, R. J.; Visscher, K.
Thin Layer Grafts of Poly[bis(methoxyethoxyethoxy)phosphazene] on Organic Polymer Surfaces
Chemistry of Materials 1992, 4, 775‑780.
272. Allcock, H. R.; Coggio, W. D.
Synthesis and Properties of High Polymeric Phosphazenes with Trimethylsilyl-Methyl Side Groups
Macromolecules 1993, 26, 764‑771.
274. Allcock, H. R.; Dodge, J. A.; Manners, I.
Poly(thiophosphazenes): New Inorganic Polymers
Macromolecules 1993, 26, 11‑16.
280. Allcock, H. R.; Nelson, C. J.; Coggio, W. D.; Manners, I.; Koros, W. J.; Walker, D. R. B.; Pessan, L. A.
Gas Permeation and Selectivity of Poly(organophosphazene) Membranes
Macromolecules 1993, 26, 1493‑1502.
284. Allcock, H. R.; Klingenberg, E. H.; Welker, M. F.
Alkylsulfonation of Cyclic and High Polymeric Phosphazenes
Macromolecules 1993, 26, 5512‑5516.
294. Allcock, H. R.; Kim, Y. B.
Synthesis, Characterization, and Modification of Poly(organophosphazenes) that Bear Both 2,2,2‑Trifluoroethoxy and Phenoxy Groups
Macromolecules 1994, 6, 516‑524.
295. Allcock, H. R.; Dudley, G. K.; Silverberg, E. N.
Stereocontrolled Polymerization of Diene Monomers within a Tris(o‑phenylene dioxy)cyclotriphosphazene Tunnel Clathrate
Macromolecules 1994, 27, 1039‑1044.
296. Allcock, H. R.; Silverberg, E. N.; Dudley, G. K.
Stereocontrolled Polymerization within a Cyclophosphazene Clathrate Tunnel
Macromolecules 1994, 27, 1033‑1038.
298. Allcock, H. R.; Coley, S. M.; Manners, I.; Visscher, K. B.; Parvez, M.
Reactivity and Polymerization of Pentachlorocyclo(carbotriphosphazene), N3P2CCl5
Inorg. Chem. 1993, 32, 5088‑5094.
303. Diefenbach, U.; Allcock, H. R.
Synthesis of Cyclo‑ and Polyphosphazenes with Pyridine Side Groups
Inorganic Chemistry 1994, 33, 4562-4565.
304. Allcock, H. R.; Coley, S. M.; Morrissey, C. T.
Synthesis and Properties of Poly[amino(carbophosphazenes)]
Macromolecules 1994, 27, 2904-2911.
308. Allcock, H. R.; Smith, D. E.; Kim, Y. B.; Fitzgerald, J. J.
Poly(organophosphazenes) Containing Allyl Side Groups: Cross‑linking by Hydrosilylation
Macromolecules 1994, 27, 5206-5215.
312. Allcock, H. R.; Silverberg, E. N.; Dudley, G. K.; Pucher, S. R.
Inclusion Polymerization Within a Tris(2,3‑naphthalenedioxy)cyclitrophosphazene Clathrate
Macromolecules 1994, 27, 7550-7555.
313. Allcock, H. R.; Kuharcik, S. E.; Morrissey, C. T.; Ngo, D. C.
Poly(monophosphazo)phosphazenes: New Polymers with N=PR3Side Groups
Macromolecules 1994, 27, 7556-7564.
322. Allcock, H. R.; Smith, D. E.
Surface Studies of Poly(organophosphazenes) Containing Diemethylsiloxane Grafts
Chemistry of Materials 1995, 7, 1469-1474.
324. Allcock, H. R.; Visscher, K. B.; Kim, Y.-B.
New Polyphosphazenes with Unsaturated Side Groups: Use as Reaction Intermediates, Cross-Linkable Polymers, and as Components of
Interpenetrating Polymer Networks
Macromolecules 1996, 2721-2728.
328. Honeyman, C. H.; Manners, I,; Morrissey, C. T.; Allcock, H. R.
Ambient Temperature Synthesis of Poly(dichlorophosphazene) with Molecular Weight Control
J. Am. Chem. Soc. 1995, 117, 7035-7036.
332. Mack, L. L.; Fitzpatrick, R. J.; Allcock, H. R.
Hydrophobicity, Hydrophilicity, and Amphiphilicity in Phosphazene Small Molecules and High Polymers: Langmuir-Blodgett Studies
Langmuir, 1997, 13, 2123-2132.
335. Allcock, H. R.; Dudley, G. K.
Lower Critical Solubility Temperature Study of Alkyl Ether-Based Polyphosphazenes
Macromolecules 1996, 29, 1313-1319.
341. Allcock, H. R.; Kuharcik, S. E.; Nelson, C. J.
The Synthesis and Characterization of Amino-organosiloxane-Bearing Polyphosphazenes: New Properties by the Elimination of Hydrogen
Bonding
Macromolecules 1996, 29, 3686-3693.
343. Allcock, H. R.; Morrissey, C. T.; Way, W. K.; Winograd, N.
Controlled Formation of Carboxylic Acid Grops at Polyphosphazene Surfaces: Oxidative and Hydrolytic Routes
Chemistry of Materials 1996, 8, 2730-2738.
345. Allcock, H. R.; O’Connor, S. J. M.; Olmeijer, D. L.; Napierala, M. E.; Cameron, C. G.
Polyphosphazenes Bearing Branched and Linear Oligoethyleneoxy Side Groups as Solid Solvents for Ionic Conduction
Macromolecules 1996, 23, 7544-7552.
347. Allcock, H. R.; Crane, C. A.; Morrissey, C. T.; Nelson, J. M.; Reeves, S. D.; Honeyman, C. H.; Manners, I.
Living Cationic Polymerization of Phosphoranimines as an Ambient Temperature route to Polyphosphazenes with Controlled Molecular Weights,
Macromolecules 1996, 29, 7740-7747.
349. Allcock, H. R.; Nelson, J. M.; Reeves, S. D.; Honeyman, C. H.; Manners, I.
Ambient Temperature Direct Synthesis of Poly(organophosphazenes) via the Living Cationic Polymerization of Organo-substituted
Phosphoranimines
Macromolecules 1997, 30, 50-56.
351. Nelson, J. M.; Allcock, H. R.
Synthesis of Triarmed Star Polyphosphazenes via the “Living" Cationic Polymerization of Phosphoranimines at Ambient Temperatures
Macromolecules 1997, 30, 1854-1856.
354. Allcock, H. R.; Reeves, S. D.; Nelson, J. M.; Crane, C. A.; Manners, I.
Polyphosphazene Block Copolymers via the Living Cationic, Ambient Temperature Polymerization of Phosphoranimines
Macromolecules 1997, 30, 2213-2215.
357. Nelson, J. M.; Allcock, H. R.; Manners, I.
Cationic Homo- and Copolymerization of Fluorophosphoranimines as an Ambient Temperature Synthetic Route to Poly(fluorophosphazenes),
[N=PF(R)]n, with Controlled Architectures
Macromolecules 1997, 30, 3191-3196.
358. Allcock, H. R.; Krause, W. E.
Polyphosphazenes with Adamantyl Side Groups
Macromolecules 1997, 30, 5683-5687.
365. Nelson, J. M.; Primrose, A. P.; Hartle, T. J.; Allcock, H. R.; Manners, I.
Synthesis and Characterization of High Tg Polyphosphazenes via Functionalized Intermediates: Potential Electro-optical Materials
Macromolecules 1998, 31, 5206-5214.
367. Allcock, H. R.; Olmeijer, D. L.; O’Connor, S. J. M.
Cation Complexation and Conductivity in Crown Ether Bearing Polyphosphazenes
Macromolecules 1998, 31, 753-759.
369. Allcock, H. R.; McIntosh, M. B.; Klingenberg, E. H.; Napierala, M. E.
Functionalized Polyphosphazenes: Phosphazenes with Pendent Tertiary Trialkylamino Groups
Macromolecules 1998, 31, 5255-5263.
371. Allcock, H. R.; Crane, C. A.; Morrissey, C. T.; Olshavsky, M. A.
A New Route to the Phosphazene Polymerization Precursors, Cl3P=NSiMe3 and (NPCl2)3
Inorganic Chemistry 1999, 38, 280-283.
377. Allcock, H. R.; Primrose, A. P.; Sunderland, N. J.; Rheingold, A. L.; Guzei, I. A.; Parvez, M.
Inclusion of Polymers within the Crystal Structure of Tris(o-phenylenedioxy) cyclotriphosphazene
Proc. Int. Phosphorus Conf. Phosphorus, Sulfur, and Silicon 1999, 144-146, 61-64.
378. Allcock, H. R.
Recent Developments with an Impact on the Future of Polyphosphazene Science and Technology
Proc. of Int. Phosphorus Conf. Phosphorus, Sulfur and Silicon 1999, 144-146, 61-64.
380. Allcock, H. R.; Laredo, W. R.; de Denus, C. R.; Taylor, J. P.
Ring-Opening Metathesis Polymerization of Phosphazene-Functionalized Norbornenes
Macromolecules 1999, 32, 7719-7725
383. Allcock, H. R; Nelson, J. M.; Prange, R.; Crane, C. A.; de Denus, C. R.
Synthesis of Telechelic Polyphosphazenes via the Ambient Temperature Living Cationic Polymerization of Amino Phosphoranimines
Macromolecules 1999, 32, 5736-5743.
385. Prange, R.; Allcock, H. R.
Telechelic Syntheses of the First Phosphazene Siloxane Block Copolymers
Macromolecules 1999, 32, 6390-6392.
388. Allcock, H. R.; de Denus, C. R.; Prange, R.; Nelson, J. M.
Synthesis of Trifluoromethyl and Methyl Phosphazene Polymers: Differences Between Polymerization and Initiator/Terminator Properties
Macromolecules 1999, 32, 7999-8004.
395. Allcock, H. R.; Reeves, S. D.; Nelson, J. M.; Manners, I.
Synthesis and Characterization of Phosphazene Di- and Tri-block Copolymers via the Controlled Cationic, Ambient Temperature Polymerization
of Phosphornimines
Macromolecules 2000, 33, 3999-4007.
396. Diefenbach, U.; Cannon, A. M.; Stromberg, B. E.; Olmeijer, B. E.; Allcock, H. R.
Synthesis and Metal Coordination of Thioether Containing Cyclo- and Poly(organophosphazenes)
J. Applied Polymer Science 2000, 78, 650-661.
397. Allcock, H. R.; Reeves, S. D.; de Denus, C. R.; Crane, C. A.
Influence of Reaction Parameters on the Living Cationic Polymerization of Phosphoranimines to Polyphosphazenes
Macromolecules 2001, 34, 748-754.
398. Chang, Y.; Lee, S. C.; Kim, C.; Reeves, S. D.; Allcock, H. R.
Synthesis and Micellar Characterization of an Amphiphilic Diblock Copolyphosphazene
Macromolecules 2001, 34, 269-274.
399. Hartle, T. J.; Sunderland, N. J.; McIntosh, M. B.; Allcock, H. R.
Phosphinimine Modifiation of Organic Polymers
Macromoleules 2000, 33, 4307-4309.
406. Prange, R.; Reeves, S. D.; Allcock, H. R.
Polyphosphazene-Polystyrene Copolymers: Block and Graft Copolymers from Polyphosphazene and Polystyrene Macromonomers
Macromolecules 2000, 33, 5763-5765.
408. Kellam, E. C.; Hofmann, M. A.; Allcock, H. R.
Synthesis of Well-Defined Cyclolinear Phosphazene-Containing Polymers via ADMET Polymerization
Macromolecules 2001, 34, 5140-5146.
412. Allcock, H. R.; Laredo, W. R.; Kellam, E. C.; Morford, R. V.
Polynorbornenes Bearing Pendent Cyclotriphosphazenes with Oligoethyleneoxy Side Groups: Behavior as Solid Polymer Electrolytes
Macromolecules 2001, 34, 787-794.
414. Allcock, H. R.; Sunderland, N. J.
Separation of Polymers and Small Molecules by Crystalline Host Systems
Macromolecules 2001, 34, 3069-3076.
415. Allcock, H. R.; de Denus, C. R.; Prange, R.; Laredo, W. R.
Synthesis of Norbornenyl Telechelic Polyphosphazenes and Ring-Opening Metathesis Polymerization of (ROMP) Reactions
Macromolecules 2001, 34, 2757-2765.
416. Allcock, H. R.; Hartle, T. J.; Taylor, J. P.; Sunderland, N. J.
Organic Polymers with Cyclophosphazene Side Groups: Influence of the Phosphazene on Physical Properties and Thermolysis
Macromolecules 2001, 34, 3896-3904.
419. Allcock, H. R.; Prange, R.
Properties of Poly(phosphazene-siloxane) Block Copolymers Synthesized via Telechelic Polyphosphazenes and Polysiloxane
Macromolecules 2001, 34, 6858-6865.
428. York, S.; Kellam, E. C.; Allcock, H. R.; Frech, R.
A Vibrational Spectroscopic Study of Lithium Triflate in Polyphosphazenes with Linear Oligoethyleneoxy Side Chains of Different Lengths
Electrochim. Acta 2001, 46, 1553-1557.
430. Allcock H. R.; Kellam, E. C.
The Incorporation of Cyclic Phosphazene Trimers into Saturated and Unsaturated Ethylene-Like Polymer Backbones
Macromolecules 2002, 35, 40-47.
433. Hofmann, M. A.; Ambler, C. M.; Maher, A. E.; Chalkova, E.; Zhou, X. Y.; Lvov, S. N.; Allcock, H. R.
Synthesis of Polyphosphazenes with Sulfonimide Side Groups
Macromolecules 2002, 35, 6490-6493.
434. Chang, Y.; Bender, J. D.; Phelps, M. V. B.; Allcock, H. R.
Synthesis and Self-Association Behavior of Biodegradable Amphiphilic Poly[bis(ethyl glycinat-N-y)phosphazene]-PEO Block Copolymers
Biomacromolecules 2002, 3, 1364-1369.
435. Allcock, H. R.; Hofmann, M. A.; Ambler, C. M.; Morford, R. V.
Phenylphosphonic Acid Functionalized Poly[aryloxyphosphazenes]
Macromolecules 2002, 35, 3483-3489.
440. Chang, Y.; Powell, E. S.; Allcock, H. R.; Park, S. M.; Kim, C.
Thermosensitive Behavior of Poly[bis(methoxyethoxyethoxy)- phosphazene]-Poly(ethylene oxide) Block Copolymers
Macromolecules 2003, 36, 2568-2570.
441. Chang, Y.; Allcock, H. R.
A Covalently Interconnected Phosphazene-Silicate Hybrid Network: Synthesis, Characterization, and Hydrogel-Related Applications
Advanced Materials 2003, 15, 537-541.
443. Chang, Y.; Prange, R.; Allcock, H. R.; Lee, S. C.; Kim, C.
Amphiphilic Poly[bis(trifluoroethoxy)phosphazene]-Poly(ethylene oxide) Block Copolymers: Synthesis and Micellar Characteristics
Macromolecules 2002, 35, 8556-8559.
446. Allcock, H. R.; Maher, A. E.; Ambler, C. M.
Side Group Exchange in Poly(organophosphazenes) with Fluoroalkoxy Substituents
Macromolecules 2003, 36, 5566-5572.
447. Maher, A. E.; Ambler, C. M.; Powell, E. S.; Allcock, H. R.
Dependency of Thermal and Mechanical Properties on the Composition of Mixed-Substituent Poly(fluoroalkoxyphosphazenes)
J. Applied Polymer Science 2004, 92, 2569-2576.
449. Allcock, H. R.; Powell, E. S.; Maher, A. E.; Prange, A. E.; de Denus, C. R.
Telechelic Polyphosphazenes: Reaction of Living Poly(dichlorophosphazene) Chains with Alkoxy and Aryloxy Phosphoranimines
Macromolecules 2004, 37, 3635-3641.
461. Allcock, H. R.; Powell, E. S.; Maher, A. E.; Berda, E. B.
Poly(methyl methacrylate)-graft-Poly[bis(trifluoroethoxy)phosphazene] Copolymers: Synthesis, Characterization, and Effects of Polyphosphazene
Incorporation
Macromolecules 2004 37, 5824-5829.
462. Maher, A. E.; Allcock, H. R.
Influence of n-Hexoxy Group on the Properties of Fluoroalkoxyphosphazene Polymers
Macromolecules 2005, 38, 641-642.
466. Allcock, H. R.; Powell, E. S.; Chang, Y.; Kim, C.
Synthesis and Micellar Behavior of Amphiphilic Polystyrene Poly[bis(methoxyethoxyethoxy)phosphazene] Block Copolymers
Macromolecules 2004, 37, 7163-7167.
B. SMALL-MOLECULE MODEL CHEMISTRY
1. Kugel, R. L.; Hodgson, W. G.; Allcock, H. R.
The Formation of Radical Anions in Fluorene Metallation
Chem. and Ind. 1962, 1649‑1650.
6. Allcock, H. R.
New Reactions of Phosphonitrilic Chloride Trimer. Substitution and Cleavage Reactions with Catechol and Triethylamine
J. Am. Chem. Soc. 1963, 85, 4050.
8. Reactions of Phosphonitrilic Chlorides with Catechol and Triethylamine
J. Am. Chem. Soc. 1964, 86, 2591‑2595.
10. Allcock, H. R.; Siegel, L. A.
Molecular Inclusion Compounds of Tris(o‑phenylenedioxy)phosphonitrilic Trimer
J. Am. Chem. Soc. 1964, 86, 5140‑5144.
13. Allcock, H. R.; Kugel, R. L.
Cyclized Products From the Reactions of Hexachlorocyclotriphosphazene (Phosphonitrilic Chloride Trimer) with Aromatic Dihydroxy, Dithiol, and
Diamino Compounds
Inorg. Chem. 1966, 5, 1016‑10.
17. Allcock, H. R.; Kugel, R. L.
Degradation of Halogenophosphazenes to a New Phosphorane System
J. Chem. Soc., Chem. Commun. 1968, 24, 1606‑1607.
18. Allcock, H. R.; Walsh, E. J.
The Base‑Catalyzed Hydrolysis of Aryloxy‑ and Alkoxycyclophosphazenes
J. Am. Chem. Soc. 1969, 91, 3102‑3103.
19. Allcock, H. R.; Kugel, R. L.
The Reaction of o‑Aminophenol with Phosphazenes
J. Am. Chem. Soc. 1969, 91, 5452‑5456.
21. Allcock, H. R.; Birdsall, W. J.
Phosphonitrilic Radical Anions
J. Am. Chem. Soc. 1969, 91, 7541‑7542.
23. Allcock, H. R.; Walsh, E. J.
The Basic Hydrolysis of Hexakis(aryloxy)cyclotriphosphazenes